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David Villa

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first time playing in a European competition.

In the team's opening group game against Utrecht, Villa netted a brace in the dying minutes of the game which subsequently ended 2–0 in Zaragoza's favour. In the round of 16, Zaragoza faced Austria Wien. The first leg ended 1–1, Villa scored in the second leg, however, the match ended 2–2 which saw the team from Vienna go through to the next stage on the away goals rule. Meanwhile, in La Liga, Villa excited Zaragoza fans on 23 September 2004 by putting the team 1–0 up against Barcelona at the Camp Nou, however, it was not to be as Barcelona came back to win the game 4–1. On 17 April 2005, Villa scored a brace which helped see off Sevilla in a 3–0 victory.



Valencia

After his success at Zaragoza, the team was in need of money, as a result, Villa made his big move to one of Spanish football's heavyweights, as a new look

Valencia under Quique Sánchez Flores parted with €12 million to secure his services in the summer of 2005. During his first game in a Valencia shirt, an Intertoto Cup match against Belgian outfit K.A.A. Gent, Villa scored the first goal in a game which Valencia won 2–0. He made his league debut for Valencia coming on as a substitute against Real Betis in a 1–0 win on 27 August 2005. The next match would see his previous team, Real Zaragoza, leading 2–1 for the majority of the match, however, on the 81st minute, Villa came on as a late substitute for Rubén Baraja and scored the equalizer within the space of a minute, earning Valencia a point as the game ended 2–2.

On 21 September, Villa would once again save Valencia a vital point by netting a brace against Barcelona at Camp Nou, actually giving his team the lead at one point after Víctor Valdés' clearance rebounded off Villa's back and into the net. On 23 October, Villa scored the winning goal against another Spanish giant, this time Real Madrid at the Santiago Bernabéu Stadium and would once again score against Barcelona, on 12 February 2006, his one goal proving enough to secure all three points in a 1–0 victory. Villa scored a goal against Deportivo de La Coruña (at the Riazor on 4 February 2006), described as "superb" by ESPN and "his best" by Sid Lowe who went on to credit it even more pointing out he achieved it "on the turn". Hitting the ball from the half way line (50 yards out) it sailed over the keepers head and into the net.

He scored his first hat-trick for Valencia against Athletic Bilbao at San Mamés in La Liga on the 23 April 2006.